When analyzing the equilibrium behavior of M/G/1 type Markov chains by transform methods, restrictive hypotheses are often made to aboid technical problems that arise in applying results from complex analysis and linear algebra. It is shown that such restrictive assumptions are unnecessary, and an analysis of these chains using generating functions is given under only the natural hypotheses that first moments (or second moments in the null recurrent case) exist. The key to the analysis is the identification of an important subspace of the space of bounded solutions of the system of homogeneous vector-valued Wiener-Hopf equations associated with the chain. In particular, the linear equations in the boundary probabilities obtained from the transform method are shown to correspond to a spectral basis of the shift operator on this subspace. Necessary and sufficient conditions under whcih the chain is ergodic, null recurrent or transient are derived in terms of properties of the matrix-valued generating functions determined by transitions of the Markov chain. In the transient case, the Martin exit boundary is identified and shown to be associated with certian eigenvalues and vectors of one of these generating functions. An equilibrium analysis of the class of G/M/1 type Markov chains by similar methods is also presented.